As soon as each bin in the histogram is visited a certain number of times [17] The calculation of some electronic processes like absorption, emission, and the general distribution of electrons in a material require us to know the number of available states per unit volume per unit energy. In equation(1), the temporal factor, \(-\omega t\) can be omitted because it is not relevant to the derivation of the DOS\(^{[2]}\). {\displaystyle E} In a system described by three orthogonal parameters (3 Dimension), the units of DOS is Energy1Volume1 , in a two dimensional system, the units of DOS is Energy1Area1 , in a one dimensional system, the units of DOS is Energy1Length1. is the oscillator frequency, T , n {\displaystyle C} 4, is used to find the probability that a fermion occupies a specific quantum state in a system at thermal equilibrium. In isolated systems however, such as atoms or molecules in the gas phase, the density distribution is discrete, like a spectral density. an accurately timed sequence of radiofrequency and gradient pulses. states per unit energy range per unit length and is usually denoted by, Where k. points is thus the number of states in a band is: L. 2 a L. N 2 =2 2 # of unit cells in the crystal . We now have that the number of modes in an interval \(dq\) in \(q\)-space equals: \[ \dfrac{dq}{\dfrac{2\pi}{L}} = \dfrac{L}{2\pi} dq\nonumber\], So now we see that \(g(\omega) d\omega =\dfrac{L}{2\pi} dq\) which we turn into: \(g(\omega)={(\frac{L}{2\pi})}/{(\frac{d\omega}{dq})}\), We do so in order to use the relation: \(\dfrac{d\omega}{dq}=\nu_s\), and obtain: \(g(\omega) = \left(\dfrac{L}{2\pi}\right)\dfrac{1}{\nu_s} \Rightarrow (g(\omega)=2 \left(\dfrac{L}{2\pi} \dfrac{1}{\nu_s} \right)\). In the field of the muscle-computer interface, the most challenging task is extracting patterns from complex surface electromyography (sEMG) signals to improve the performance of myoelectric pattern recognition. for 2 ( ) 2 h. h. . m. L. L m. g E D = = 2 ( ) 2 h. As a crystal structure periodic table shows, there are many elements with a FCC crystal structure, like diamond, silicon and platinum and their Brillouin zones and dispersion relations have this 48-fold symmetry. In the channel, the DOS is increasing as gate voltage increase and potential barrier goes down. Through analysis of the charge density difference and density of states, the mechanism affecting the HER performance is explained at the electronic level. unit cell is the 2d volume per state in k-space.) (a) Fig. Figure \(\PageIndex{1}\)\(^{[1]}\). 0000076287 00000 n One state is large enough to contain particles having wavelength . Getting the density of states for photons, Periodicity of density of states with decreasing dimension, Density of states for free electron confined to a volume, Density of states of one classical harmonic oscillator. 0000005040 00000 n V_3(k) = \frac{\pi^{3/2} k^3}{\Gamma(3/2+1)} = \frac{\pi \sqrt \pi}{\frac{3 \sqrt \pi}{4}} k^3 = \frac 4 3 \pi k^3 Browse other questions tagged, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site. The Wang and Landau algorithm has some advantages over other common algorithms such as multicanonical simulations and parallel tempering. The linear density of states near zero energy is clearly seen, as is the discontinuity at the top of the upper band and bottom of the lower band (an example of a Van Hove singularity in two dimensions at a maximum or minimum of the the dispersion relation). Equation(2) becomes: \(u = A^{i(q_x x + q_y y)}\). 0000004547 00000 n endstream endobj startxref 3 In general the dispersion relation An important feature of the definition of the DOS is that it can be extended to any system. where 0000004792 00000 n 0000061802 00000 n To finish the calculation for DOS find the number of states per unit sample volume at an energy [15] Now we can derive the density of states in this region in the same way that we did for the rest of the band and get the result: \[ g(E) = \dfrac{1}{2\pi^2}\left( \dfrac{2|m^{\ast}|}{\hbar^2} \right)^{3/2} (E_g-E)^{1/2}\nonumber\]. g a So, what I need is some expression for the number of states, N (E), but presumably have to find it in terms of N (k) first. As for the case of a phonon which we discussed earlier, the equation for allowed values of \(k\) is found by solving the Schrdinger wave equation with the same boundary conditions that we used earlier. by V (volume of the crystal). 0 {\displaystyle D_{1D}(E)={\tfrac {1}{2\pi \hbar }}({\tfrac {2m}{E}})^{1/2}} ( [1] The Brillouin zone of the face-centered cubic lattice (FCC) in the figure on the right has the 48-fold symmetry of the point group Oh with full octahedral symmetry. New York: Oxford, 2005. d Since the energy of a free electron is entirely kinetic we can disregard the potential energy term and state that the energy, \(E = \dfrac{1}{2} mv^2\), Using De-Broglies particle-wave duality theory we can assume that the electron has wave-like properties and assign the electron a wave number \(k\): \(k=\frac{p}{\hbar}\), \(\hbar\) is the reduced Plancks constant: \(\hbar=\dfrac{h}{2\pi}\), \[k=\frac{p}{\hbar} \Rightarrow k=\frac{mv}{\hbar} \Rightarrow v=\frac{\hbar k}{m}\nonumber\]. 0000008097 00000 n k 0000003837 00000 n Fig. Hope someone can explain this to me. MathJax reference. For quantum wires, the DOS for certain energies actually becomes higher than the DOS for bulk semiconductors, and for quantum dots the electrons become quantized to certain energies. , where s is a constant degeneracy factor that accounts for internal degrees of freedom due to such physical phenomena as spin or polarization. n = {\displaystyle N(E)\delta E} If the volume continues to decrease, \(g(E)\) goes to zero and the shell no longer lies within the zone. trailer << /Size 173 /Info 151 0 R /Encrypt 155 0 R /Root 154 0 R /Prev 385529 /ID[<5eb89393d342eacf94c729e634765d7a>] >> startxref 0 %%EOF 154 0 obj << /Type /Catalog /Pages 148 0 R /Metadata 152 0 R /PageLabels 146 0 R >> endobj 155 0 obj << /Filter /Standard /R 3 /O ('%dT%\).) /U (r $h3V6 ) /P -1340 /V 2 /Length 128 >> endobj 171 0 obj << /S 627 /L 739 /Filter /FlateDecode /Length 172 0 R >> stream m {\displaystyle g(i)} The number of states in the circle is N(k') = (A/4)/(/L) . 0000075509 00000 n Asking for help, clarification, or responding to other answers. 0000073571 00000 n Why are physically impossible and logically impossible concepts considered separate in terms of probability? as a function of k to get the expression of Calculating the density of states for small structures shows that the distribution of electrons changes as dimensionality is reduced. The area of a circle of radius k' in 2D k-space is A = k '2. 10 10 1 of k-space mesh is adopted for the momentum space integration. and small k. space - just an efficient way to display information) The number of allowed points is just the volume of the . k Such periodic structures are known as photonic crystals. 0000069197 00000 n . Freeman and Company, 1980, Sze, Simon M. Physics of Semiconductor Devices. 0000065501 00000 n In 2-dim the shell of constant E is 2*pikdk, and so on. B Tour Start here for a quick overview of the site Help Center Detailed answers to any questions you might have Meta Discuss the workings and policies of this site Immediately as the top of 0000075117 00000 n ( Hi, I am a year 3 Physics engineering student from Hong Kong. 2 0000138883 00000 n 0000004498 00000 n {\displaystyle \Omega _{n,k}} {\displaystyle E} For a one-dimensional system with a wall, the sine waves give. They fluctuate spatially with their statistics are proportional to the scattering strength of the structures. The product of the density of states and the probability distribution function is the number of occupied states per unit volume at a given energy for a system in thermal equilibrium. Design strategies of Pt-based electrocatalysts and tolerance strategies in fuel cells: a review. The number of quantum states with energies between E and E + d E is d N t o t d E d E, which gives the density ( E) of states near energy E: (2.3.3) ( E) = d N t o t d E = 1 8 ( 4 3 [ 2 m E L 2 2 2] 3 / 2 3 2 E). we multiply by a factor of two be cause there are modes in positive and negative \(q\)-space, and we get the density of states for a phonon in 1-D: \[ g(\omega) = \dfrac{L}{\pi} \dfrac{1}{\nu_s}\nonumber\], We can now derive the density of states for two dimensions. m = Muller, Richard S. and Theodore I. Kamins. E 1vqsZR(@ta"|9g-//kD7//Tf`7Sh:!^* k Systems with 1D and 2D topologies are likely to become more common, assuming developments in nanotechnology and materials science proceed. ) with respect to the energy: The number of states with energy Find an expression for the density of states (E). 2 In simple metals the DOS can be calculated for most of the energy band, using: \[ g(E) = \dfrac{1}{2\pi^2}\left( \dfrac{2m^*}{\hbar^2} \right)^{3/2} E^{1/2}\nonumber\]. In 1-dim there is no real "hyper-sphere" or to be more precise the logical extension to 1-dim is the set of disjoint intervals, {-dk, dk}. for a particle in a box of dimension Figure \(\PageIndex{3}\) lists the equations for the density of states in 4 dimensions, (a quantum dot would be considered 0-D), along with corresponding plots of DOS vs. energy. ``e`Jbd@ A+GIg00IYN|S[8g Na|bu'@+N~]"!tgFGG`T l r9::P Py -R`W|NLL~LLLLL\L\.?2U1. BoseEinstein statistics: The BoseEinstein probability distribution function is used to find the probability that a boson occupies a specific quantum state in a system at thermal equilibrium. k-space divided by the volume occupied per point. ) is the Boltzmann constant, and Even less familiar are carbon nanotubes, the quantum wire and Luttinger liquid with their 1-dimensional topologies. (a) Roadmap for introduction of 2D materials in CMOS technology to enhance scaling, density of integration, and chip performance, as well as to enable new functionality (e.g., in CMOS + X), and 3D . Recovering from a blunder I made while emailing a professor. | D Thus the volume in k space per state is (2/L)3 and the number of states N with |k| < k . , by. 0000003644 00000 n D Use the Fermi-Dirac distribution to extend the previous learning goal to T > 0. Vk is the volume in k-space whose wavevectors are smaller than the smallest possible wavevectors decided by the characteristic spacing of the system. ) d Though, when the wavelength is very long, the atomic nature of the solid can be ignored and we can treat the material as a continuous medium\(^{[2]}\). P(F4,U _= @U1EORp1/5Q':52>|#KnRm^ BiVL\K;U"yTL|P:~H*fF,gE rS/T}MF L+; L$IE]$E3|qPCcy>?^Lf{Dg8W,A@0*Dx\:5gH4q@pQkHd7nh-P{E R>NLEmu/-.$9t0pI(MK1j]L~\ah& m&xCORA1`#a>jDx2pd$sS7addx{o Local variations, most often due to distortions of the original system, are often referred to as local densities of states (LDOSs). Are there tables of wastage rates for different fruit and veg? 0000006149 00000 n , the expression for the 3D DOS is. inside an interval 0000064265 00000 n n 0000063429 00000 n > 1 The density of states is defined by hb```f`d`g`{ B@Q% {\displaystyle E'} V_1(k) = 2k\\ The above expression for the DOS is valid only for the region in \(k\)-space where the dispersion relation \(E =\dfrac{\hbar^2 k^2}{2 m^{\ast}}\) applies. 0000005490 00000 n The number of modes Nthat a sphere of radius kin k-space encloses is thus: N= 2 L 2 3 4 3 k3 = V 32 k3 (1) A useful quantity is the derivative with respect to k: dN dk = V 2 k2 (2) We also recall the . Figure \(\PageIndex{2}\)\(^{[1]}\) The left hand side shows a two-band diagram and a DOS vs.\(E\) plot for no band overlap. k {\displaystyle s/V_{k}} {\displaystyle \Omega _{n}(E)} According to crystal structure, this quantity can be predicted by computational methods, as for example with density functional theory. dfy1``~@6m=5c/PEPg?\B2YO0p00gXp!b;Zfb[ a`2_ += Computer simulations offer a set of algorithms to evaluate the density of states with a high accuracy. The dispersion relation is a spherically symmetric parabola and it is continuously rising so the DOS can be calculated easily. 0000073179 00000 n It was introduced in 1979 by Likes and in 1983 by Ljunggren and Twieg.. / includes the 2-fold spin degeneracy. Some condensed matter systems possess a structural symmetry on the microscopic scale which can be exploited to simplify calculation of their densities of states. This procedure is done by differentiating the whole k-space volume as. E The general form of DOS of a system is given as, The scheme sketched so far only applies to monotonically rising and spherically symmetric dispersion relations. 0000067967 00000 n 0000066746 00000 n Express the number and energy of electrons in a system in terms of integrals over k-space for T = 0. 0000004890 00000 n Fisher 3D Density of States Using periodic boundary conditions in . 0000061387 00000 n of the 4th part of the circle in K-space, By using eqns. }.$aoL)}kSo@3hEgg/>}ze_g7mc/g/}?/o>o^r~k8vo._?|{M-cSh~8Ssc>]c\5"lBos.Y'f2,iSl1mI~&8:xM``kT8^u&&cZgNA)u s&=F^1e!,N1f#pV}~aQ5eE"_\T6wBj kKB1$hcQmK!\W%aBtQY0gsp],Eo . phonons and photons). m In a system described by three orthogonal parameters (3 Dimension), the units of DOS is Energy 1 Volume 1 , in a two dimensional system, the units of DOS is Energy 1 Area 1 , in a one dimensional system, the units of DOS is Energy 1 Length 1. D The distribution function can be written as. 0000004645 00000 n N Theoretically Correct vs Practical Notation. Can Martian regolith be easily melted with microwaves? + j ] . ) %W(X=5QOsb]Jqeg+%'$_-7h>@PMJ!LnVSsR__zGSn{$\":U71AdS7a@xg,IL}nd:P'zi2b}zTpI_DCE2V0I`tFzTPNb*WHU>cKQS)f@t ,XM"{V~{6ICg}Ke~` E Omar, Ali M., Elementary Solid State Physics, (Pearson Education, 1999), pp68- 75;213-215. The volume of the shell with radius \(k\) and thickness \(dk\) can be calculated by simply multiplying the surface area of the sphere, \(4\pi k^2\), by the thickness, \(dk\): Now we can form an expression for the number of states in the shell by combining the number of allowed \(k\) states per unit volume of \(k\)-space with the volume of the spherical shell seen in Figure \(\PageIndex{1}\). Bulk properties such as specific heat, paramagnetic susceptibility, and other transport phenomena of conductive solids depend on this function. {\displaystyle n(E)} 2 0000007661 00000 n Density of States ECE415/515 Fall 2012 4 Consider electron confined to crystal (infinite potential well) of dimensions a (volume V= a3) It has been shown that k=n/a, so k=kn+1-kn=/a Each quantum state occupies volume (/a)3 in k-space. . d Finally the density of states N is multiplied by a factor k Density of States in 3D The values of k x k y k z are equally spaced: k x = 2/L ,. %PDF-1.5 % The wavelength is related to k through the relationship. %%EOF k {\displaystyle d} 0000141234 00000 n Figure 1. This is illustrated in the upper left plot in Figure \(\PageIndex{2}\). Elastic waves are in reference to the lattice vibrations of a solid comprised of discrete atoms. E k This expression is a kind of dispersion relation because it interrelates two wave properties and it is isotropic because only the length and not the direction of the wave vector appears in the expression. 2 In more advanced theory it is connected with the Green's functions and provides a compact representation of some results such as optical absorption. In general it is easier to calculate a DOS when the symmetry of the system is higher and the number of topological dimensions of the dispersion relation is lower. The density of states appears in many areas of physics, and helps to explain a number of quantum mechanical phenomena. 0000010249 00000 n for linear, disk and spherical symmetrical shaped functions in 1, 2 and 3-dimensional Euclidean k-spaces respectively. h[koGv+FLBl to To derive this equation we can consider that the next band is \(Eg\) ev below the minimum of the first band\(^{[1]}\). Solution: . E MzREMSP1,=/I LS'|"xr7_t,LpNvi$I\x~|khTq*P?N- TlDX1?H[&dgA@:1+57VIh{xr5^ XMiIFK1mlmC7UP< 4I=M{]U78H}`ZyL3fD},TQ[G(s>BN^+vpuR0yg}'z|]` w-48_}L9W\Mthk|v Dqi_a`bzvz[#^:c6S+4rGwbEs3Ws,1q]"z/`qFk 3 0000062205 00000 n 0 n A complete list of symmetry properties of a point group can be found in point group character tables. Can archive.org's Wayback Machine ignore some query terms? S_3(k) = \frac {d}{dk} \left( \frac 4 3 \pi k^3 \right) = 4 \pi k^2 {\displaystyle L\to \infty } , and thermal conductivity $$, and the thickness of the infinitesimal shell is, In 1D, the "sphere" of radius $k$ is a segment of length $2k$ (why? [9], Within the Wang and Landau scheme any previous knowledge of the density of states is required. If you preorder a special airline meal (e.g. Connect and share knowledge within a single location that is structured and easy to search. 0000004743 00000 n ) New York: W.H. which leads to \(\dfrac{dk}{dE}={(\dfrac{2 m^{\ast}E}{\hbar^2})}^{-1/2}\dfrac{m^{\ast}}{\hbar^2}\) now substitute the expressions obtained for \(dk\) and \(k^2\) in terms of \(E\) back into the expression for the number of states: \(\Rightarrow\frac{1}{{(2\pi)}^3}4\pi{(\dfrac{2 m^{\ast}}{\hbar^2})}^2{(\dfrac{2 m^{\ast}}{\hbar^2})}^{-1/2})E(E^{-1/2})dE\), \(\Rightarrow\frac{1}{{(2\pi)}^3}4\pi{(\dfrac{2 m^{\ast}E}{\hbar^2})}^{3/2})E^{1/2}dE\). Interesting systems are in general complex, for instance compounds, biomolecules, polymers, etc. The results for deriving the density of states in different dimensions is as follows: 3D: g ( k) d k = 1 / ( 2 ) 3 4 k 2 d k 2D: g ( k) d k = 1 / ( 2 ) 2 2 k d k 1D: g ( k) d k = 1 / ( 2 ) 2 d k I get for the 3d one the 4 k 2 d k is the volume of a sphere between k and k + d k. V 85 0 obj <> endobj On this Wikipedia the language links are at the top of the page across from the article title. {\displaystyle q=k-\pi /a} The Kronig-Penney Model - Engineering Physics, Bloch's Theorem with proof - Engineering Physics. Measurements on powders or polycrystalline samples require evaluation and calculation functions and integrals over the whole domain, most often a Brillouin zone, of the dispersion relations of the system of interest. New York: John Wiley and Sons, 2003. 1721 0 obj <>/Filter/FlateDecode/ID[]/Index[1708 32]/Info 1707 0 R/Length 75/Prev 305995/Root 1709 0 R/Size 1740/Type/XRef/W[1 2 1]>>stream 1 0000004841 00000 n a k dN is the number of quantum states present in the energy range between E and x N I cannot understand, in the 3D part, why is that only 1/8 of the sphere has to be calculated, instead of the whole sphere. F In other systems, the crystalline structure of a material might allow waves to propagate in one direction, while suppressing wave propagation in another direction. It is mathematically represented as a distribution by a probability density function, and it is generally an average over the space and time domains of the various states occupied by the system. LDOS can be used to gain profit into a solid-state device. V [12] For longitudinal phonons in a string of atoms the dispersion relation of the kinetic energy in a 1-dimensional k-space, as shown in Figure 2, is given by. {\displaystyle \Omega _{n,k}} ( {\displaystyle D_{n}\left(E\right)} ca%XX@~ Thus, 2 2. In materials science, for example, this term is useful when interpreting the data from a scanning tunneling microscope (STM), since this method is capable of imaging electron densities of states with atomic resolution. For different photonic structures, the LDOS have different behaviors and they are controlling spontaneous emission in different ways. E In anisotropic condensed matter systems such as a single crystal of a compound, the density of states could be different in one crystallographic direction than in another. 0000033118 00000 n {\displaystyle a} is temperature. {\displaystyle T} the energy-gap is reached, there is a significant number of available states. endstream endobj startxref E+dE. Equation(2) becomes: \(u = A^{i(q_x x + q_y y+q_z z)}\). xref q 4dYs}Zbw,haq3r0x {\displaystyle N} E contains more information than In 1-dimensional systems the DOS diverges at the bottom of the band as The density of states is once again represented by a function \(g(E)\) which this time is a function of energy and has the relation \(g(E)dE\) = the number of states per unit volume in the energy range: \((E, E+dE)\). Upper Saddle River, NJ: Prentice Hall, 2000. = k 0000068788 00000 n = Here, The smallest reciprocal area (in k-space) occupied by one single state is: n {\displaystyle m} n Its volume is, $$ Recap The Brillouin zone Band structure DOS Phonons . We begin with the 1-D wave equation: \( \dfrac{\partial^2u}{\partial x^2} - \dfrac{\rho}{Y} \dfrac{\partial u}{\partial t^2} = 0\). This value is widely used to investigate various physical properties of matter. E where m is the electron mass. s 0000017288 00000 n electrons, protons, neutrons). In spherically symmetric systems, the integrals of functions are one-dimensional because all variables in the calculation depend only on the radial parameter of the dispersion relation. of this expression will restore the usual formula for a DOS. Notice that this state density increases as E increases. ) E 0000004596 00000 n If you have any doubt, please let me know, Copyright (c) 2020 Online Physics All Right Reseved, Density of states in 1D, 2D, and 3D - Engineering physics, It shows that all the As the energy increases the contours described by \(E(k)\) become non-spherical, and when the energies are large enough the shell will intersect the boundaries of the first Brillouin zone, causing the shell volume to decrease which leads to a decrease in the number of states. Two other familiar crystal structures are the body-centered cubic lattice (BCC) and hexagonal closed packed structures (HCP) with cubic and hexagonal lattices, respectively. F 0000005540 00000 n 0000063841 00000 n Derivation of Density of States (2D) Recalling from the density of states 3D derivation k-space volume of single state cube in k-space: k-space volume of sphere in k-space: V is the volume of the crystal. b8H?X"@MV>l[[UL6;?YkYx'Jb!OZX#bEzGm=Ny/*byp&'|T}Slm31Eu0uvO|ix=}/__9|O=z=*88xxpvgO'{|dO?//on ~|{fys~{ba? for m =1rluh tc`H The photon density of states can be manipulated by using periodic structures with length scales on the order of the wavelength of light. The density of states is directly related to the dispersion relations of the properties of the system. The . where \(m ^{\ast}\) is the effective mass of an electron. becomes E 0000062614 00000 n Those values are \(n2\pi\) for any integer, \(n\). k V The density of state for 2D is defined as the number of electronic or quantum states per unit energy range per unit area and is usually defined as . with respect to k, expressed by, The 1, 2 and 3-dimensional density of wave vector states for a line, disk, or sphere are explicitly written as. 0000004903 00000 n Learn more about Stack Overflow the company, and our products. The number of k states within the spherical shell, g(k)dk, is (approximately) the k space volume times the k space state density: 2 3 ( ) 4 V g k dk k dkS S (3) Each k state can hold 2 electrons (of opposite spins), so the number of electron states is: 2 3 ( ) 8 V g k dk k dkS S (4 a) Finally, there is a relatively . N ) In a quantum system the length of will depend on a characteristic spacing of the system L that is confining the particles. Hence the differential hyper-volume in 1-dim is 2*dk. 4 is the area of a unit sphere. E , other for spin down. endstream endobj 86 0 obj <> endobj 87 0 obj <> endobj 88 0 obj <>/ExtGState<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>> endobj 89 0 obj <> endobj 90 0 obj <> endobj 91 0 obj [/Indexed/DeviceRGB 109 126 0 R] endobj 92 0 obj [/Indexed/DeviceRGB 105 127 0 R] endobj 93 0 obj [/Indexed/DeviceRGB 107 128 0 R] endobj 94 0 obj [/Indexed/DeviceRGB 105 129 0 R] endobj 95 0 obj [/Indexed/DeviceRGB 108 130 0 R] endobj 96 0 obj [/Indexed/DeviceRGB 108 131 0 R] endobj 97 0 obj [/Indexed/DeviceRGB 112 132 0 R] endobj 98 0 obj [/Indexed/DeviceRGB 107 133 0 R] endobj 99 0 obj [/Indexed/DeviceRGB 106 134 0 R] endobj 100 0 obj [/Indexed/DeviceRGB 111 135 0 R] endobj 101 0 obj [/Indexed/DeviceRGB 110 136 0 R] endobj 102 0 obj [/Indexed/DeviceRGB 111 137 0 R] endobj 103 0 obj [/Indexed/DeviceRGB 106 138 0 R] endobj 104 0 obj [/Indexed/DeviceRGB 108 139 0 R] endobj 105 0 obj [/Indexed/DeviceRGB 105 140 0 R] endobj 106 0 obj [/Indexed/DeviceRGB 106 141 0 R] endobj 107 0 obj [/Indexed/DeviceRGB 112 142 0 R] endobj 108 0 obj [/Indexed/DeviceRGB 103 143 0 R] endobj 109 0 obj [/Indexed/DeviceRGB 107 144 0 R] endobj 110 0 obj [/Indexed/DeviceRGB 107 145 0 R] endobj 111 0 obj [/Indexed/DeviceRGB 108 146 0 R] endobj 112 0 obj [/Indexed/DeviceRGB 104 147 0 R] endobj 113 0 obj <> endobj 114 0 obj <> endobj 115 0 obj <> endobj 116 0 obj <>stream